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1.1 This guide describes the determination of approximate optimum SO₃ for maximum performance as a result of substituting calcium sulfate for a portion of the cement.

1.2 This guide refers to the sulfur trioxide (SO₃) content of the cement only. Slag cements and occasionally other hydraulic cements can contain sulfide or other forms of sulfur. The determination of SO₃ content by rapid methods may include these other forms, and may therefore produce a significant error. If a significant error occurs, analyze the cement for SO₃ content using the reference test method of Test Methods C114 for sulfur trioxide.

1.3 Values stated as SI units are to be regarded as standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

3.1 The purpose of this guide is to estimate the SO₃ content for a hydraulic cement that gives maximum performance. The value obtained is one way to establish an appropriate level of sulfate in the manufacture of cements specified in Specifications C150/C150M, C595/C595M, and C1157/C1157M.

3.2 The SO₃ content of a cement giving maximum performance is different at different ages, with different performance criteria and with different materials such supplementary cementitious materials and chemical admixtures. A manufacturer can choose the performance criteriato determine optimum SO₃ content. This optimum SO₃ content may be a compromise between different ages and different performance criteria.

3.3 This guide indicates optimum SO₃ content for cement, optionally in presence of supplementary cementitious materials and admixtures. Several alternate methods are allowed: compressive strength of concrete or mortar, heat of hydration of paste or mortar, and drying shrinkage of mortar.

3.4 It should not be assumed that the optimum SO₃ estimated in this guide is the same SO₃ content for optimum performance of a concrete prepared in the field using the same materials. The optimum SO₃ is influenced by parameters such as ambient and fresh concrete temperature, admixtures, and supplementary cementitious materials.

3.5 The guide is applicable to cements specified in Specifications C150/C150M, C595/C595M, and C1157/C1157M.