ASTM-D6144 Historical Revision Information
Standard Test Method for Analysis of AMS (alpha-Methylstyrene) by Capillary Gas Chromatography

ASTM-D6144 - 2008 EDITION - SUPERSEDED
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Standard Test Method for Analysis of AMS (α-Methylstyrene) by Capillary Gas Chromatography
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Scope

1.1 This test method covers the determination of the purity of AMS (α-methylstyrene) by gas chromatography. Calibration of the gas chromatography system is done by the external standard calibration technique.

1.2 This test method has been found applicable to the measurement of impurities such as cumene, 3-methyl-2-cyclopentene-1-one, n-propylbenzene, tert-butylbenzene, sec-butylbenzene, cis-2-phenyl-2-butene, acetophenone, 1-phenyl-1-butene, 2-phenyl-2-propanol, trans-2-phenyl-2-butene, m-cymene, p-cymene, and phenol, which are common to the manufacturing process of AMS. The method has also been found applicable for the determination of para-tertiary-butylcatechol typically added as a stabilizer to AMS. The impurities in AMS can be analyzed over a range of 5 to 800 mg/kg by this method. (See Table 1.) The limit of detection for these impurities is typically in the range of 5 to 10 mg/kg. (See Table 1.)

1.3 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E 29.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.

Significance and Use

This test method is suitable for setting specifications on the materials referenced in 1.2 and for use as an internal quality control tool where AMS is produced or is used in a manufacturing process. It may also be used in development or research work involving AMS.

This test method is useful in determining the purity of AMS with normal impurities present. If extremely high boiling or unusual impurities are present in the AMS, this test method would not necessarily detect them and the purity calculation would be erroneous.

Keywords

acetophenone; alpha methylstyrene; AMS; analysis by gas chromatography; benzene; butenylbenzene; butylbenzene; catechol; cumene; cymene; phenol; propylbenzene; toluene; Gas chromatography (GC)--paints/related coatings/materials; Purity analysis--paints/related coatings/materials; AMS (&alph;-Methylstyrene); Methylstyrene; ICS Number Code 71.040.50 (Physicochemical methods of analysis)

To find similar documents by ASTM Volume:

06.04 (Paint -- Solvents; Aromatic Hydrocarbons)

To find similar documents by classification:

71.040.50 (Physicochemical methods of analysis Including spectrophotometric and chromatographic analysis)

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Document Number

ASTM-D6144-08

Revision Level

2008 EDITION

Status

Superseded

Modification Type

Revision

Publication Date

June 1, 2008

Document Type

Test Method

Page Count

5 pages

Committee Number

D16.07