ASTM-D6159 Historical Revision Information
Standard Test Method for Determination of Hydrocarbon Impurities in Ethylene by Gas Chromatography

ASTM-D6159 - 1997 R12 EDITION - SUPERSEDED
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Standard Test Method for Determination of Hydrocarbon Impurities in Ethylene by Gas Chromatography
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Scope

1.1 This test method covers the determination of methane, ethane, propane, propene, acetylene, iso-butane, propadiene, butane, trans-2-butene, butene-1, isobutene, cis-2-butene, methyl acetylene and 1,3-butadiene in high-purity ethylene. The purity of the ethylene can be calculated by subtracting the total percentage of all impurities from 100.00 %. Since this test method does not determine all possible impurities such as CO, CO2, H2O, alcohols, nitrogen oxides, and carbonyl sulfide, as well as hydrocarbons higher than decane, additional tests may be necessary to fully characterize the ethylene sample.

1.2 Data are reported in this test method as ppmV (parts per million by volume). This test method was evaluated in an interlaboratory cooperative study in the concentration range of 4 to 340 ppmV (2 to 204 mg/kg). The participants in the interlaboratory cooperative study reported the data in non-SI units. Wherever possible, SI units are included.

1.3 This standard dose not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Significance and Use

4.1 High-purity ethylene is required as a feedstock for some manufacturing processes and the presence of trace amounts of certain hydrocarbon impurities can have deleterious effects. This test method is suitable for setting specifications, for use as an internal quality control tool, and for use in development or research work.

4.2 This test method does not detect such impurities as H2O, CO, CO2, and alcohols that may be present in the sample. Hydrocarbons higher than n-decane cannot be analyzed by this test method, if present in the sample. Test Method D2504 addresses the analysis of noncondensable gases and Test Method D2505 addresses the analysis of CO2. Guide D5234 describes all potential impurities present in ethylene. These standards should be consulted when determining the total concentration of impurities in ethylene.

Keywords

ethylene; gas chromatography; hydrocarbon impurities; ICS Number Code 71.080.01 (Organic chemicals in general)

To find similar documents by ASTM Volume:

05.02 (Petroleum Products and Lubricants (II): D3711 - D6122)

05.03 (Petroleum Products and Lubricants (III): D6138 - D6971)

To find similar documents by classification:

71.040.50 (Physicochemical methods of analysis Including spectrophotometric and chromatographic analysis)

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Document Number

ASTM-D6159-97(2012)

Revision Level

1997 R12 EDITION

Status

Superseded

Modification Type

Reapproval

Publication Date

Dec. 1, 2012

Document Type

Test Method

Page Count

5 pages

Committee Number

D02.D0.02