ASTM-D7845 Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography/Mass Spectrometry

ASTM-D7845 - 2020 EDITION - CURRENT
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Standard Test Method for Determination of Chemical Species in Marine Fuel Oil by Multidimensional Gas Chromatography/Mass Spectrometry
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Scope

1.1 This test method covers the quantitative determination of a variety of chemical species in marine fuel oil (bunker fuel oil) by gas chromatography/mass spectrometry. By using the same conditions and by selecting required mass spectral selected ions, the test method may be used for the determination of other species than those for which precision statements and limits of detection have been established.

1.2 An example list of chemical species for which a limit of quantification has been determined by means of this test method is given in Table 1.

1.3 Other refinery hydrocarbon fractions and their mixtures may be tested using the same test method conditions. However, the precision of this test method reflects the compounds in Table 1.

1.4 Results are reported to the nearest 1.0 mg/kg.

1.5 The values stated in SI units are to be regarded as standard.

1.5.1 Exception—Non-SI values are given for psig.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Significance and Use

5.1 The test method allows the quantitation of chemical species at low levels in marine fuel oils and cutter stocks. A great many types and concentrations of chemical species are found in marine fuel oils. A root cause relationship between the presence of such species or their concentration in fuels and any failure modes allegedly induced by the use of these fuels has not been established. This test method is necessary to establish test conditions required for future ISO 8217:2010 as defined in section 5.5 and Annex B item (d). Additional compounds may be determined by using the same conditions and by selecting required mass spectral selected ions, accordingly.

Keywords

bunker fuel oil; gas chromatography; GC/MS; marine fuel oil; mass spectrometry;

To find similar documents by ASTM Volume:

05.04 (Petroleum Products and Lubricants (IV): D6973 - latest)

05.05 (Combustion Characteristics; Manufactured Carbon and Graphite Products; Catalysts)

To find similar documents by classification:

47.020.20 (Marine engines and propulsion systems Standards for internal combustion engines for general use, see 27.020)

75.160.20 (Liquid fuels Including gasoline, diesel, kerosene, etc.)

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Document Number

ASTM-D7845-20

Revision Level

2020 EDITION

Status

Current

Modification Type

Revision

Publication Date

July 1, 2020

Document Type

Test Method

Page Count

12 pages

Committee Number

D02.04.0M