ASTM-E2781 Standard Practice for Evaluation of Methods for Determination of Kinetic Parameters by Calorimetry and Differential Scanning Calorimetry

ASTM-E2781 - 2024 EDITION - CURRENT
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Standard Practice for Evaluation of Methods for Determination of Kinetic Parameters by Calorimetry and Differential Scanning Calorimetry
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Scope

1.1 The purpose of this practice is to provide kinetic parameters for reference materials used to evaluate thermal analysis methods, apparatus, and software where enthalpy and temperature are measured. This practice addresses both exothermic and endothermic, nth order, and autocatalytic reactions.

1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Significance and Use

5.1 The kinetic parameters provided in this practice may be used to evaluate the performance of a standard, apparatus, technique, or software for the determination parameters (such as Test Methods E698, E1641, E2041, or E2070) using thermal analysis techniques such as differential scanning calorimetry, and accelerating rate calorimetry (Guide E1981). The results obtained may be compared to the values provided by this practice.

Note 4: Not all reference materials are suitable for each measurement technique.

Keywords

activation energy; kinetics; pre-exponential factor; reaction order; thermal analysis;

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Document Number

ASTM-E2781-24

Revision Level

2024 EDITION

Status

Current

Modification Type

Revision

Publication Date

April 4, 2024

Document Type

Practice

Page Count

3 pages

Committee Number

E37.02