ASTM-G186 › Standard Test Method for Determining Whether Gas-Leak-Detector Fluid Solutions Can Cause Stress Corrosion Cracking of Brass Alloys
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1.1 This test method covers an accelerated test method for evaluating the tendency of gas leak detection fluids (LDFs) to cause stress corrosion cracking (SCC) of brass components in compressed gas service.
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.
Significance and Use
5.1 Brass components are routinely used in compressed gas service for valves, pressure regulators, connectors and many other components. Although soft brass is not susceptible to ammonia SCC, work-hardened brass is susceptible if its hardness exceeds about 54 HR 30T (55HRB) (Rockwell scale). Normal assembly of brass components should not induce sufficient work hardening to cause susceptibility to ammonia SCC. However, it is has been observed that over-tightening of the components will render them susceptible to SCC, and the problem becomes more severe in older components that have been tightened many times. In this test, the specimens are obtained in the hardened condition and are strained beyond the elastic limit to accelerate the tendency towards SCC.
5.2 It is normal practice to use LDFs to check pressurized systems to assure that leaking is not occurring. LDFs are usually aqueous solutions containing surfactants that will form bubbles at the site of a leak. If the LDF contains ammonia or other agent that can cause SCC in brass, serious damage can occur to the system that will compromise its safety and integrity.
5.3 It is important to test LDFs to assure that they do not cause SCC of brass and to assure that the use of these products does not compromise the integrity of the pressure containing system.
5.4 It has been found that corrosion of brass is necessary before SCC can occur. The reason for this is that the corrosion process results in cupric and cuprous ions accumulating in the electrolyte. Therefore, adding copper metal and cuprous oxide (Cu2O) to the aqueous solution accelerates the SCC process if agents that cause SCC are present. However, adding these components to a solution that does not cause SCC will not make stressed brass crack.
5.5 Repeated application of the solution to the specimen followed by a drying period causes the components in the solution to concentrate thereby further increasing the rate of cracking. This also simulates service where a system may be tested many times during its life. These features of the test method accelerate the test and allow an answer to be obtained more rapidly.
5.6 This test method applies only to brasses. Successful passage of this test does not assure that the LDF will be acceptable for use on other alloy systems such as stainless steels or aluminum alloys.
brass alloys; bubble solutions; C-ring specimens; CDA272; gas-leak-detector solutions; leak detector solutions; soap solutions; stress corrosion cracking;; ICS Number Code 77.060 (Corrosion of metals)
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2005 R16 EDITION
June 1, 2016