ISO-6145-10 › Gas analysis - Preparation of calibration gas mixtures using dynamic volumetric methods - Part 10: Permeation method
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This part of ISO 6145 specifies a dynamic method using permeation membranes for the preparation of calibration gas mixtures containing component mole fractions ranging from 10−9 and 10−6. A relative expanded uncertainty of 2,5 % of the component mole fraction can be achieved using this method. In the mole fraction range considered, it is difficult to maintain some gas mixtures, for example in cylinders, in a stable state. It is therefore desirable to prepare the calibration gas immediately before use, and to transfer it by the shortest possible path to the place where it is to be used. This technique has been successfully applied in generating low content calibration gas mixtures of, for example, sulfur dioxide (SO2), nitrogen dioxide (NO2) and benzene (C6H6) in air.
If the carrier gas flow is measured as a gas mass-flow, the preparation of calibration gas mixtures using permeation tubes is a dynamic-gravimetric method which gives contents in mole fractions.
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71.040.40 (Chemical analysis Including analysis of gases and surface chemical analysis)
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Document Number
ISO 6145-10:2002
Revision Level
1ST EDITION
Status
Current
Publication Date
Feb. 1, 2002
Committee Number
ISO/TC 158