ISO-11369 › Water quality - Determination of selected plant treatment agents - Method using high performance liquid chromatography with UV detection after solid-liquid extraction
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This International Standard describes a method for the determination of organic plant treatment agents in drinking and ground water using high performance liquid chromatography (HPLC) with UV detection after solid-liquid extraction.
The method described in this International Standard is applicable to the determination of selected plant treatment agents and some of their main degradation products (metabolites) in drinking water with a validated reporting limit of about 0,1 μg/l. Limited additional data indicate that it can be extended to 0,05 μg/l (see table 1 for examples). The method may be extended to include additional substances and ground water, provided the method is validated for each individual case.
The selection of the plant treatment agents and main degradation products in table 1 has been made according to the knowledge at the time of the interlaboratory trial (1992). Data for some other substances are given in annex A.
Table 1 - Plant treatment agents to which this lntematlonal Standard applies | ||||
---|---|---|---|---|
Name | Molecular formula | Molar mass | CAS No.1) | Substance family2) |
Atrazine | C8H14CIN5 | 215,7 | 001912-24-9 | T |
Chlorotoluron | C10H13CIN20 | 212,7 | 015545-48-9 | H |
Cyanazine** | C9H13CIN5 | 240,7 | 021725-46-2 | T |
Desethylatrazine* | C8H9CIN5 | 186,6 | 006190-65-4 | T |
Diuron | C9H10Cl2N2O | 233,1 | 000330-54-1 | H |
Hexazinone** | C12H20N4O2 | 252,3 | 051235-04-2 | T |
Isoproturon | C12H18N2O | 206,3 | 034123-59-6 | H |
Linuron | C9H10Cl2N2O2 | 249,1 | 000330-55-2 | H |
Metazachlor | C14H16ClN2O3 | 277,8 | 067129-08-2 | A |
Methabenzthiazuron | C10H11N3OS | 221,3 | 018691-97-9 | H |
Metobromuron** | C9H11BrN2O2 | 259,1 | 003060-89-7 | H |
Metolachlor | C15H22ClNO2 | 283,8 | 051218-45-2 | A |
Metoxuron** | C10H13ClN2O2 | 228,7 | 19937-59-8 | H |
Monolinuron | C9H11ClN2O2 | 214,6 | 1746-81-2 | H |
Sebutylazine** | C9H15ClN5 | 228,7 | 00728-69-3 | T |
Simazine | C7H12ClN5 | 201,7 | 000122-34-9 | T |
Terbutylazine | C9H16ClN5 | 229,7 | 005915-41-3 | T |
1) CAS No.: Chemical abstracts number | ||||
2) Substance family: T: Triazine; H: Phenylurea herbicide; A: substituted anilide | ||||
*: Main degradation product of atrazine | ||||
**: Not included in the performance data |
To find similar documents by classification:
13.060.50 (Examination of water for chemical substances)
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Document Number
ISO 11369:1997
Revision Level
1ST EDITION
Status
Current
Publication Date
Aug. 1, 1997
Committee Number
ISO TC 147/SC 2/WG 36