ASTM-D4457 Historical Revision Information
Standard Test Method for Determination of Dichloromethane and 1,1,1-Trichloroethane in Paints and Coatings by Direct Injection into a Gas Chromatograph

ASTM-D4457 - 2002 EDITION - SUPERSEDED
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Standard Test Method for Determination of Dichloromethane and 1,1,1-Trichloroethane in Paints and Coatings by Direct Injection into a Gas Chromatograph (Withdrawn 2019)
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Scope

1.1 This test method covers the determination of total amount of dichloromethane or 1,1,1-trichloroethane, or both, in paints and coatings. It has been evaluated for cellulose nitrate, alkyd, vinyl, and styrene-butadiene systems. It has not yet been evaluated for other formulations, but is believed to be applicable. The established working range of this test method is from 31 to 65 % for 1,1,1-trichloroethane and 32 to 78 % for dichloromethane. There is no reason to believe it will not work outside of these ranges. The presence of 1-propanol in paints and coatings requires the use of a different internal standard. (See also Practice E 260.)

1.2 The values stated in inch-pound units are to be regarded as the standard. The values given in parentheses are for information only.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7.

Significance and Use

Use of 1,1,1-trichloroethane and dichloromethane, which do not measurably contribute to the atmospheric oxidant level, is a way for industry to meet government or other regulations on volatile organic compounds. This test method is designed to determine the content of these halohydrocarbon solvents in paints and coatings. That content can subsequently be used in calculating the volatile organic compound content of a coating.

Keywords

chlorinated hydrocarbons in paints by gas chromatograph; dichloromethane, in paints; exempted solvent in paints; gas chromatograph, halohydrocarbon; 1,1,1-trichloroethane, in paints; ICS Number Code 87.040 (Paints and varnishes)

To find similar documents by ASTM Volume:

06.01 (Paint -- Tests for Chemical, Physical, and Optical Properties; Appearance)

To find similar documents by classification:

87.040 (Paints and varnishes Including coating powders, paint coatings and protective paint systems)

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Document Number

ASTM-D4457-02

Revision Level

2002 EDITION

Status

Superseded

Publication Date

Jan. 10, 2002

Document Type

Test Method

Page Count

4 pages

Committee Number

D01.21