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Scope

1.1 This test method covers the determination of the total nonaromatic hydrocarbons and trace monocyclic aromatic hydrocarbons in toluene, mixed xylenes, and p-xylenes by gas chromatography. The purity of toluene, mixed xylenes, or p-xylenes can also be calculated. Calibration of the gas chromatographic system is done by the external standard calibration technique. A similar test method, using the internal standard calibration technique, is Test Method D 2360.

1.2 Total aliphatic hydrocarbons containing 1 through 10 carbon atoms (methane through decanes) can be detected by this test method at concentrations ranging from 0.001 to 2.500 weight %.

1.2.1 A small amount of benzene in mixed xylenes or p-xylenes may not be distinguished from the nonaromatics and the concentrations are determined as a composite (see 6.1).

1.3 Monocyclic aromatic hydrocarbon impurities containing 6 through 10 carbon atoms (benzene through C ₁₀ aromatics) can be detected by this test method at individual concentrations ranging from 0.001 to 1.000 weight %.

1.4 The following applies to all specified limits in this test method: for purposes of determining conformance with this test method, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statement, see Section 9.

Significance and Use

Determining the type and amount of hydrocarbon impurities remaining from the manufacture of toluene, mixed xylenes, and p-xylenes used as chemical intermediates and solvents is often required. This test method is suitable for setting specifications and for use as an internal quality control tool where these products are produced or are used. Typical impurities are: alkanes containing 1 to 10 carbons atoms, benzene, toluene, ethylbenzene (EB), xylenes, and aromatic hydrocarbons containing nine carbon atoms.

5.1.1 Refer to Test Method D 2306 for determining the C₈ aromatic hydrocarbon distribution in mixed xylenes.

Purity is commonly reported by subtracting the determined expected impurities from 100.00. However, a gas chromatographic analysis cannot determine absolute purity if unknown or undetected components are contained within the material being examined.

This test method is similar to Test Method D 2360, however, interlaboratory testing has indicated a bias may exist between the two methods. Therefore the user is cautioned that the two methods may not give comparable results.

Keywords

aromatics; external standard; gas chromatography; impurities; purity; toluene; xylenes; ICS Number Code 71.040.50 (Physicochemical methods of analysis); 71.080.15 (Aromatic hydrocarbons)

To find similar documents by ASTM Volume:

06.04 (Paint -- Solvents; Aromatic Hydrocarbons)

To find similar documents by classification:

71.040.50 (Physicochemical methods of analysis Including spectrophotometric and chromatographic analysis)

71.080.15 (Aromatic hydrocarbons)

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