ASTM-D874 › Historical Revision Information
Standard Test Method for Sulfated Ash from Lubricating Oils and Additives
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Scope
1.1 This test method covers the determination of the sulfated ash from unused lubricating oils containing additives and from additive concentrates used in compounding. These additives usually contain one or more of the following metals: barium, calcium, magnesium, zinc, potassium, sodium, and tin. The elements sulfur, phosphorus, and chlorine can also be present in combined form.
1.2 Application of this test method to sulfated ash levels below 0.02 mass % is restricted to oils containing ashless additives. The lower limit of the test method is 0.005 mass % sulfated ash.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
Significance and Use
5.1 The sulfated ash can be used to indicate the concentration of known metal-containing additives in new oils. When phosphorus is absent, barium, calcium, magnesium, sodium and potassium are converted to their sulfates and tin (stannic) and zinc to their oxides (Note 5). Sulfur and chlorine do not interfere, but when phosphorus is present with metals, it remains partially or wholly in the sulfated ash as metal phosphates.
5.2 Because of above inter-element interferences, experimentally obtained sulfated ash values may differ from sulfated ash values calculated from elemental analysis. The formation of such non-sulfated species is dependent on the temperature of ashing, time ashed, and the composition of metal compounds present in oils. Hence, sulfated ash requirement generally should not be used in product specifications without a clear understanding between a buyer and a seller of the unreliability of an ash value as an indicator of the total metallic compound content.3
Keywords
additives; ash; lubricating oils; ICS Number Code 75.100 (Lubricants, industrial oils and related products)
To find similar documents by ASTM Volume:
05.01 (Petroleum Products and Lubricants (I): D56 - D3710)
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Document Number
ASTM-D874-13
Revision Level
2013 EDITION
Status
Superseded
Modification Type
Revision
Publication Date
Aug. 1, 2013
Document Type
Test Method
Page Count
5 pages
Committee Number
D02.03