ASTM-D4742 Standard Test Method for Oxidation Stability of Gasoline Automotive Engine Oils by Thin-Film Oxygen Uptake (TFOUT)

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Standard Test Method for Oxidation Stability of Gasoline Automotive Engine Oils by Thin-Film Oxygen Uptake (TFOUT)



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1.1 This test method evaluates the oxidation stability of engine oils for gasoline automotive engines. This test, run at 160 °C, utilizes a high pressure reactor pressurized with oxygen along with a metal catalyst package, a fuel catalyst, and water in a partial simulation of the conditions to which an oil may be subjected in a gasoline combustion engine. This test method can be used for engine oils with viscosity in the range from 4 mm2/s (cSt) to 21 mm2/s (cSt) at 100 °C, including re-refined oils.

1.2 This test method is not a substitute for the engine testing of an engine oil in established engine tests, such as Sequence IIID.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3.1 Exception—Pressure units are provided in psig, and dimensions are provided in inches in Annex A1, because these are the industry accepted standard and the apparatus is built according to the figures shown.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Sections 7 and 8.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Significance and Use

5.1 This test method is used to evaluate oxidation stability of lubricating base oils with additives in the presence of chemistries similar to those found in gasoline engine service. Test results on some ASTM reference oils have been found to correlate with sequence IIID engine test results in hours for a 375 % viscosity increase.5 The test does not constitute a substitute for engine testing, which measures wear, oxidation stability, volatility, and deposit control characteristics of lubricants. Properly interpreted, the test may provide input on the oxidation stability of lubricants under simulated engine chemistry.

5.2 This test method is intended to be used as a bench screening test and quality control tool for lubricating base oil manufacturing, especially for re-refined lubricating base oils. This test method is useful for quality control of oxidation stability of re-refined oils from batch to batch.

5.3 This test method is useful for screening formulated oils prior to engine tests. Within similar additive chemistry and base oil types, the ranking of oils in this test appears to be predictive of ranking in engine tests. When oils having completely different additive chemistry or base oil type are compared, oxidation stability results may not reflect the actual engine test result.

5.4 Other oxidation stability test methods have demonstrated that soluble metal catalyst supplies are very inconsistent and they have significant effects on the test results. Thus, for test comparisons, the same source and same batch of metal naphthenates shall be used.

Note 2: It is also recommended as a good research practice not to use different batches of the fuel component in test comparisons.


oxidation stability; oxygen uptake; sequence IIID engine simulation; TFOUT;; ICS Number Code 75.100 (Lubricants, industrial oils and related products)

To find similar documents by ASTM Volume:

05.02 (Petroleum Products and Lubricants (II): D3711 - D6122)

To find similar documents by classification:

75.100 (Lubricants, industrial oils and related products Including mineral oils, fluids for metal working and for temporary protection against corrosion Lubrication systems, see 21.260 Insulating oils, see 29.035.40)

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Publication Date

July 15, 2017

Document Type

Test Method

Page Count

11 pages

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