ASTM-E478 Historical Revision Information
Standard Test Methods for Chemical Analysis of Copper Alloys

ASTM-E478 - 2008 EDITION - SUPERSEDED
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Standard Test Methods for Chemical Analysis of Copper Alloys
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Scope

1.1 These test methods cover the chemical analysis of copper alloys having chemical compositions within the following limits:

ElementConcentration, %
Aluminum12.0 max
Antimony 1.0 max
Arsenic 1.0 max
Cadmium 1.5 max
Cobalt 1.0 max
Copper40.0 min
Iron 6.0 max
Lead27.0 max
Manganese 6.0 max
Nickel50.0 max
Phosphorus 1.0 max
Silicon 5.0 max
Sulfur 0.1 max
Tin20.0 max
Zinc50.0 max

1.2 The test methods appear in the following order:

Sections
Aluminum by the Carbamate Extraction-Ethyl-
enedinitrilotetraacetate Titrimetric Test Method [2 % to 12 %]
71-78
Copper by the Combined Electrodeposition Gravimetric and Oxalyldihydrazide Photometric Test Method [50 %, minimum]10-18
Iron by the 1,10-Phenanthroline Photometric Test Method [0.003 % to 1.25 %]19-28
Lead by Atomic Absorption Spectrometry [0.002 % to 15 %]90-100
Lead by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2.0 % to 30.0 %]29-36
Nickel by the Dimethylglyoxime Extraction Photometric Test Method [0.03 % to 5.0 %]37-46
Nickel by the Dimethylglyoxime Gravimetric Test Method [4 % to 50 %]55-62
Silver in Silver-Bearing Copper by Atomic Absorption Spectrometry [0.01 % to 0.12 %]101-112
Tin by the Iodotimetric Titration Test Method [0.5 % to 20 %]63-70
Tin by the Phenylfluorone Photometric Test Method [0.01 % to 1.0 %]113-123
Zinc by Atomic Absorption Spectrometry [0.2 % to 2 %]79-89
Zinc by the Ethylenedinitrilotetraacetic Acid (EDTA) Titrimetric Test Method [2 % to 40 %]47-54

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

10.1 This test method covers the determination of copper in concentrations greater than 50 %.

19.1 This test method covers the determination of iron in concentrations from 0.003 % to 1.25 %.

29.1 This test method covers the determination of lead in concentrations from 2.0 % to 30.0 %.

37.1 This test method covers the determination of nickel in concentrations from 0.03 % to 5.0 %.

47.1 This test method covers the determination of zinc in the range from 2 % to 40 %.

55.1 This test method covers the determination of nickel in concentrations from 4 % to 50 %.

63.1 This test method covers the determination of tin in concentrations from 0.5 % to 20 %.

71.1 This test method covers the determination of aluminum in concentrations from 2 % to 12 %.

79.1 This test method covers the determination of zinc in concentrations from 0.02 % to 2 %.

90.1 This test method covers the determination of lead in concentrations from 0.002 % to 15 %.

101.1 This test method covers the determination of silver in concentrations from 0.01 % to 0.12 %.

113.1 This test method covers the determination of tin in concentrations from 0.01 % to 1.0 %.

Significance and Use

These test methods for the chemical analysis of metals and alloys are primarily intended as referee methods to test such materials for compliance with compositional specifications. It is assumed that all who use these methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.

Keywords

atomic absorption spectrometry; copper; photometric; titrimetric; Aluminum content--Cu/Cu alloys; Copper content--Cu/Cu alloys; Iron content--Cu/Cu alloys; Lead content--Cu/Cu alloys; Nickel content--Cu/Cu alloys; Silver content--Cu/Cu alloys; Tin content--Cu/Cu alloys; Zinc content--Cu/Cu alloys; Copper alloy (chemical analysis); ICS Number Code 77.040.30 (Chemical analysis of metals); 77.120.30 (Copper and copper alloys)

To find similar documents by ASTM Volume:

03.05 (Analytical Chemistry for Metals, Ores, and Related Materials: E 32 - latest)

To find similar documents by classification:

77.040.30 (Chemical analysis of metals Chemical analysis in general, see 71.040.40 Chemical analysis of ferrous metals, see 77.080 Chemical analysis of ferroalloys, see 77.100 Chemical analysis of non-ferrous metals, see 77.120 Chemical analysis of sintered metals and hard metals, see 77.160)

77.120.30 (Copper and copper alloys)

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Document Number

ASTM-E478-08

Revision Level

2008 EDITION

Status

Superseded

Modification Type

Revision

Publication Date

Dec. 15, 2008

Document Type

Test Method

Page Count

21 pages

Committee Number

E01.05